Three-Dimensional Cu-Ni Composite Superamphiphobic Surface via Electrodeposition and Fluorosilane Modification

A superamphiphobic (SAP) surface was fabricated by electrodepositing Cu-Ni micro-nano particles on aluminum substrate and modifying via 1H, 1H, 2H, 2H-perfluorodecyltrimethoxysilane. Scanning electron microscopy, X-ray diffraction, energy-dispersive X-ray spectroscopy, and Fourier-transform infrared spectroscopy were employed to investigate the morphology and chemical composition. The results showed that the SAP surface had three-dimensional micro-nano structures and exhibited a maximum water contact angle of 160.0\begin{document}$ ^{\circ} $\end{document}, oil contact angle of 151.6\begin{document}$ ^{\circ} $\end{document}, a minimum water slide angle of 0\begin{document}$ ^{\circ} $\end{document} and oil slide angle of 9\begin{document}$ ^{\circ} $\end{document}. The mechanical strength and chemical stability of the SAP surface were tested further. The experimental results showed that the SAP surface presented excellent resistance to wear, prominent acid-resistance and alkali-resistance, self-cleaning and anti-fouling properties.     

Energy level alignment of blended organic semiconductors and electrodes at the interface

The energy level alignment of a blended mixture of organic semiconductors is often depicted as having a common vacuum level. However, this is not a universal phenomenon among the vast number of organic semiconductors that currently exist, as in many cases the energy levels align via the Fermi level. In this report, the energy level alignments of the mixtures; poly(9-vinylcarbazole) (PVK) and 2,7-bis(diphenylphosphoryl)-9,9′-spirobifluorene (SPPO13) and poly(3-hexylthiophene-2,5-diyl) (P3HT) and SPPO13, with varying SPPO13 concentrations, are measured. It was found that the blended systems exhibit two different vacuum levels with the dipole between the PVK and SPPO13 increasing with the SPPO13 concentration, whilst the P3HT and SPPO13 vacuum levels only experience a small change. This is attributed to the decreasing electronic screening with increasing SPPO13 concentration. These new observations have an important implication in our understanding of interfacial behaviour for blended systems commonly used in various organic electronic devices.     

基于FEAHP法和模糊理想点法的B2R低碳物流决策方法

在对B2R低碳物流服务商选择决策过程中,构建低碳经济发展下的评价指标体系,建立模糊拓展层次分析法(FEAHP)模型对计算各个指标权重,然后根据模糊理想点法(FTOPSIS)的思想,获得各备择方案与理想解的靠近程度对B2R低碳物流服务商进行排序,选择出最佳的合作伙伴。最后,通过算例证明FEAHP和FTOPSIS具有可靠性和实用性。     

Direct observation of the hysteretic Fermi level modulation in monolayer MoS2 field effect transistors

The hysteresis in the transfer curve of MoS₂ has significant impact on the device performance. However, the hysteresis mechanism is still not clear. Here, we investigate the hysteresis of the monolayer MoS₂ by probing the local Fermi level variations as a function of the back gate voltage in different atmosphere using the Kelvin probe microscopy. While the Fermi level of the MoS₂ in air is much lower than that in vacuum, both the MoS₂ devices in vacuum and air show large Fermi level hysteresis. The Fermi level hysteresis direction is clock-wise, identical to that observed in the transfer curves. Both the hysteresis in Fermi level and transfer curve can be explained consistently by taking into account the charge trapping. Our findings confirm that carrier density modulation in MoS₂ plays a vital role in the hysteresis, and provide insight into the hysteresis mechanism for the optimization of the device performance.     

插值法在低温温度测量中的应用

依托建立的低温精馏装置,针对低温环境中温度测量问题,提出一种基于LabVIEW的低温温度测量方法。该方法将插值法引入到数据分析中,通过软件编程实现数据处理、显示、存储等功能。经过理论分析与实验对比,该方法准确度提高到0.01 K,可移植性强,是低温环境中温度测量的可行方法。     

采用加权直方图分析和蒙特卡洛重采样法对自由能级的校正研究

本文采用加权直方图分析方法和蒙特卡洛重采样方法进行自由基校正研究. 生成的自由能表面几乎可以收敛到具有足够采样情况的精准表面，并且比常规的加权直方图分析校正方法能更稳定地处理采样不足的情况，为检测能级校正表面的不确定性提供指南，并且定义了明确的标准用以确定能改善其视觉效果的自由能表面平滑程度. 本文通过水中的丙氨酸二肽和KillerRed蛋白质子转移的自由能图证明该方法的优势，说明蒙特卡洛重采样法可以作为在产生自由能表面实际的系统中的实用工具.     

引入Si掺杂层调控InGaAs/GaAs表面量子点的光学特性

在InGaAs/GaAs表面量子点(SQDs)的GaAs势垒层中引入Si掺杂层,以研究Si掺杂对InGaAs/GaAs SQDs光学特性的影响。荧光发光谱(PL)测量结果显示,InGaAs/GaAs SQDs的发光强烈依赖于Si掺杂浓度。随着掺杂浓度的增加, SQDs的PL峰值位置先红移后蓝移; PL峰值能量与激光激发强度的立方根依赖关系由线性向非线性转变;通过组态交互作用方法发现SQDs的PL峰位蓝移减弱;时间分辨荧光光谱显示了从非线性衰减到线性衰减的转变。以上结果说明Si掺杂能够填充InGaAs SQDs的表面态,并且改变表面费米能级钉扎效应和SQDs的荧光辐射特性。本研究为深入理解与InGaAs SQDs的表面敏感特性关联的物理机制和载流子动力学过程,以及扩大InGaAs/GaAs SQDs传感器的应用提供了实验依据。     

低抗凝肝素寡糖的制备、结构表征及免疫活性评价

以猪肠黏膜来源低抗凝肝素为原料,采用苄酯碱水解法制备了寡糖.通过聚丙烯酰胺凝胶电泳(PAGE)、高效凝胶渗透色谱(HPGPC)-多角激光光散射法(MALLs)联用、核磁共振波谱(NMR)和液相色谱-质谱(LC-MS)联用技术对所制备寡糖的分子量分布及化学结构进行了表征.以该寡糖对活化X因子(FXa)及人凝血酶(FⅡa)活性的抑制作用评价了其抗凝血活性,并通过测定其对RAW264.7巨噬细胞吞噬能力及NO释放量的影响评价其免疫活性.结果表明,所制备寡糖的聚合度分布于2~22之间,平均分子质量为5300,无明显的抗凝血活性,但具有显著的免疫增强活性.